Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange

Host—guest assemblies can exploit stimuli-responsive guest binding and release for molecular recognition, but are typically governed by thermodynamics alone. Here, the authors design macrocycles with removable and exchangeable anion caps, allowing for the kinetic trapping and on-demand exchange of g...

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Autores principales: Yoko Sakata, Chiho Murata, Shigehisa Akine
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/1a4c7f327ef84aeab97e5ed244cb2f9c
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