Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange

Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange

Host—guest assemblies can exploit stimuli-responsive guest binding and release for molecular recognition, but are typically governed by thermodynamics alone. Here, the authors design macrocycles with removable and exchangeable anion caps, allowing for the kinetic trapping and on-demand exchange of g...

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Autores principales: Yoko Sakata, Chiho Murata, Shigehisa Akine
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Q
Acceso en línea:https://doaj.org/article/1a4c7f327ef84aeab97e5ed244cb2f9c
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spelling oai:doaj.org-article:1a4c7f327ef84aeab97e5ed244cb2f9c2021-12-02T15:38:34ZAnion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange10.1038/ncomms160052041-1723https://doaj.org/article/1a4c7f327ef84aeab97e5ed244cb2f9c2017-07-01T00:00:00Zhttps://doi.org/10.1038/ncomms16005https://doaj.org/toc/2041-1723Host—guest assemblies can exploit stimuli-responsive guest binding and release for molecular recognition, but are typically governed by thermodynamics alone. Here, the authors design macrocycles with removable and exchangeable anion caps, allowing for the kinetic trapping and on-demand exchange of guest ions.Yoko SakataChiho MurataShigehisa AkineNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yoko Sakata
Chiho Murata
Shigehisa Akine
Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange
description Host—guest assemblies can exploit stimuli-responsive guest binding and release for molecular recognition, but are typically governed by thermodynamics alone. Here, the authors design macrocycles with removable and exchangeable anion caps, allowing for the kinetic trapping and on-demand exchange of guest ions.
format article
author Yoko Sakata
Chiho Murata
Shigehisa Akine
author_facet Yoko Sakata
Chiho Murata
Shigehisa Akine
author_sort Yoko Sakata
title Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange
title_short Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange
title_full Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange
title_fullStr Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange
title_full_unstemmed Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange
title_sort anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/1a4c7f327ef84aeab97e5ed244cb2f9c
work_keys_str_mv AT yokosakata anioncappedmetallohostallowsextremelyslowguestuptakeandondemandaccelerationofguestexchange
AT chihomurata anioncappedmetallohostallowsextremelyslowguestuptakeandondemandaccelerationofguestexchange
AT shigehisaakine anioncappedmetallohostallowsextremelyslowguestuptakeandondemandaccelerationofguestexchange
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