Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange
Host—guest assemblies can exploit stimuli-responsive guest binding and release for molecular recognition, but are typically governed by thermodynamics alone. Here, the authors design macrocycles with removable and exchangeable anion caps, allowing for the kinetic trapping and on-demand exchange of g...
Guardado en:
Autores principales: | Yoko Sakata, Chiho Murata, Shigehisa Akine |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2017
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Materias: | |
Acceso en línea: | https://doaj.org/article/1a4c7f327ef84aeab97e5ed244cb2f9c |
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