Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes
The Alder–ene type reaction is a synthetically useful, redox-neutral method to rearrange carbon–carbon bonds, but has only been demonstrated intramolecularly. Here the authors present a method to perform the Alder–ene type reaction intermolecularly with cylcopentenes and silylynes, proceeding enanti...
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| Auteurs principaux: | , , , , |
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| Format: | article |
| Langue: | EN |
| Publié: |
Nature Portfolio
2021
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| Accès en ligne: | https://doaj.org/article/1c1cf55e2fd54ec5bd5abcb7fd7bbe80 |
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