Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes

The Alder–ene type reaction is a synthetically useful, redox-neutral method to rearrange carbon–carbon bonds, but has only been demonstrated intramolecularly. Here the authors present a method to perform the Alder–ene type reaction intermolecularly with cylcopentenes and silylynes, proceeding enanti...

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Autores principales:	Dongquan Zhang, Miaomiao Li, Jiajia Li, Aijun Lin, Hequan Yao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/1c1cf55e2fd54ec5bd5abcb7fd7bbe80
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spelling	oai:doaj.org-article:1c1cf55e2fd54ec5bd5abcb7fd7bbe802021-11-21T12:35:36ZRhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes10.1038/s41467-021-26955-92041-1723https://doaj.org/article/1c1cf55e2fd54ec5bd5abcb7fd7bbe802021-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-26955-9https://doaj.org/toc/2041-1723The Alder–ene type reaction is a synthetically useful, redox-neutral method to rearrange carbon–carbon bonds, but has only been demonstrated intramolecularly. Here the authors present a method to perform the Alder–ene type reaction intermolecularly with cylcopentenes and silylynes, proceeding enantioselectively via rhodium catalysis.Dongquan ZhangMiaomiao LiJiajia LiAijun LinHequan YaoNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-7 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Dongquan Zhang Miaomiao Li Jiajia Li Aijun Lin Hequan Yao Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes
description	The Alder–ene type reaction is a synthetically useful, redox-neutral method to rearrange carbon–carbon bonds, but has only been demonstrated intramolecularly. Here the authors present a method to perform the Alder–ene type reaction intermolecularly with cylcopentenes and silylynes, proceeding enantioselectively via rhodium catalysis.
format	article
author	Dongquan Zhang Miaomiao Li Jiajia Li Aijun Lin Hequan Yao
author_facet	Dongquan Zhang Miaomiao Li Jiajia Li Aijun Lin Hequan Yao
author_sort	Dongquan Zhang
title	Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes
title_short	Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes
title_full	Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes
title_fullStr	Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes
title_full_unstemmed	Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes
title_sort	rhodium-catalyzed intermolecular enantioselective alder–ene type reaction of cyclopentenes with silylacetylenes
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/1c1cf55e2fd54ec5bd5abcb7fd7bbe80
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Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes

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