Stereospecific Si-C coupling and remote control of axial chirality by enantioselective palladium-catalyzed hydrosilylation of maleimides

Catalytic asymmetric hydrosilylation of internal alkenes has proven elusive due to more favourable double bond reduction or isomerization. Here, the authors show an enantioselective Si-C coupling by hydrosilylation of activated alkenes using a palladium/phosphoramidite catalyst affording axially chi...

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Autores principales: Xing-Wei Gu, Yu-Li Sun, Jia-Le Xie, Xing-Ben Wang, Zheng Xu, Guan-Wu Yin, Li Li, Ke-Fang Yang, Li-Wen Xu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/22450d70f92445818b71e7af0f1e2de3
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