Selective hydrosilylation of allyl chloride with trichlorosilane

Hydrosilylation of allyl chloride with trichlorosilane is industrially important but often proceeds unselectively. Here a Rh(I) catalyst which achieves 99% selectivity on gram scale is described, based on bidentate phosphine ligands.

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Autores principales: Koya Inomata, Yuki Naganawa, Zhi An Wang, Kei Sakamoto, Kazuhiro Matsumoto, Kazuhiko Sato, Yumiko Nakajima
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/248c7532ea7146be83c0519f270e6480
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