Selective hydrosilylation of allyl chloride with trichlorosilane

Hydrosilylation of allyl chloride with trichlorosilane is industrially important but often proceeds unselectively. Here a Rh(I) catalyst which achieves 99% selectivity on gram scale is described, based on bidentate phosphine ligands.

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Autores principales:	Koya Inomata, Yuki Naganawa, Zhi An Wang, Kei Sakamoto, Kazuhiro Matsumoto, Kazuhiko Sato, Yumiko Nakajima
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/248c7532ea7146be83c0519f270e6480
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spelling	oai:doaj.org-article:248c7532ea7146be83c0519f270e64802021-12-02T15:36:11ZSelective hydrosilylation of allyl chloride with trichlorosilane10.1038/s42004-021-00502-52399-3669https://doaj.org/article/248c7532ea7146be83c0519f270e64802021-05-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00502-5https://doaj.org/toc/2399-3669Hydrosilylation of allyl chloride with trichlorosilane is industrially important but often proceeds unselectively. Here a Rh(I) catalyst which achieves 99% selectivity on gram scale is described, based on bidentate phosphine ligands.Koya InomataYuki NaganawaZhi An WangKei SakamotoKazuhiro MatsumotoKazuhiko SatoYumiko NakajimaNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Koya Inomata Yuki Naganawa Zhi An Wang Kei Sakamoto Kazuhiro Matsumoto Kazuhiko Sato Yumiko Nakajima Selective hydrosilylation of allyl chloride with trichlorosilane
description	Hydrosilylation of allyl chloride with trichlorosilane is industrially important but often proceeds unselectively. Here a Rh(I) catalyst which achieves 99% selectivity on gram scale is described, based on bidentate phosphine ligands.
format	article
author	Koya Inomata Yuki Naganawa Zhi An Wang Kei Sakamoto Kazuhiro Matsumoto Kazuhiko Sato Yumiko Nakajima
author_facet	Koya Inomata Yuki Naganawa Zhi An Wang Kei Sakamoto Kazuhiro Matsumoto Kazuhiko Sato Yumiko Nakajima
author_sort	Koya Inomata
title	Selective hydrosilylation of allyl chloride with trichlorosilane
title_short	Selective hydrosilylation of allyl chloride with trichlorosilane
title_full	Selective hydrosilylation of allyl chloride with trichlorosilane
title_fullStr	Selective hydrosilylation of allyl chloride with trichlorosilane
title_full_unstemmed	Selective hydrosilylation of allyl chloride with trichlorosilane
title_sort	selective hydrosilylation of allyl chloride with trichlorosilane
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/248c7532ea7146be83c0519f270e6480
work_keys_str_mv	AT koyainomata selectivehydrosilylationofallylchloridewithtrichlorosilane AT yukinaganawa selectivehydrosilylationofallylchloridewithtrichlorosilane AT zhianwang selectivehydrosilylationofallylchloridewithtrichlorosilane AT keisakamoto selectivehydrosilylationofallylchloridewithtrichlorosilane AT kazuhiromatsumoto selectivehydrosilylationofallylchloridewithtrichlorosilane AT kazuhikosato selectivehydrosilylationofallylchloridewithtrichlorosilane AT yumikonakajima selectivehydrosilylationofallylchloridewithtrichlorosilane
_version_	1718386341384814592

Selective hydrosilylation of allyl chloride with trichlorosilane

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