Selective hydrosilylation of allyl chloride with trichlorosilane
Hydrosilylation of allyl chloride with trichlorosilane is industrially important but often proceeds unselectively. Here a Rh(I) catalyst which achieves 99% selectivity on gram scale is described, based on bidentate phosphine ligands.
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Autores principales: | Koya Inomata, Yuki Naganawa, Zhi An Wang, Kei Sakamoto, Kazuhiro Matsumoto, Kazuhiko Sato, Yumiko Nakajima |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2021
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Materias: | |
Acceso en línea: | https://doaj.org/article/248c7532ea7146be83c0519f270e6480 |
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