Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry

Criegee intermediates have received much attention in atmospheric chemistry because of their importance in ozonolysis mechanisms. Here, using quantum mechanical kinetics, the authors reveal an unexpectedly fast mechanistic pathway for unimolecular reactions of large stabilized Criegee intermediates.

Saved in:
Bibliographic Details
Main Authors: Bo Long, Junwei Lucas Bao, Donald G. Truhlar
Format: article
Language:EN
Published: Nature Portfolio 2019
Subjects:
Q
Online Access:https://doaj.org/article/2884648f595e4ddd8db9b61c5cd7842e
Tags: Add Tag
No Tags, Be the first to tag this record!