Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry

Criegee intermediates have received much attention in atmospheric chemistry because of their importance in ozonolysis mechanisms. Here, using quantum mechanical kinetics, the authors reveal an unexpectedly fast mechanistic pathway for unimolecular reactions of large stabilized Criegee intermediates.

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Detalles Bibliográficos
Autores principales:	Bo Long, Junwei Lucas Bao, Donald G. Truhlar
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/2884648f595e4ddd8db9b61c5cd7842e
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spelling	oai:doaj.org-article:2884648f595e4ddd8db9b61c5cd7842e2021-12-02T16:58:19ZRapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry10.1038/s41467-019-09948-72041-1723https://doaj.org/article/2884648f595e4ddd8db9b61c5cd7842e2019-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09948-7https://doaj.org/toc/2041-1723Criegee intermediates have received much attention in atmospheric chemistry because of their importance in ozonolysis mechanisms. Here, using quantum mechanical kinetics, the authors reveal an unexpectedly fast mechanistic pathway for unimolecular reactions of large stabilized Criegee intermediates.Bo LongJunwei Lucas BaoDonald G. TruhlarNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Bo Long Junwei Lucas Bao Donald G. Truhlar Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry
description	Criegee intermediates have received much attention in atmospheric chemistry because of their importance in ozonolysis mechanisms. Here, using quantum mechanical kinetics, the authors reveal an unexpectedly fast mechanistic pathway for unimolecular reactions of large stabilized Criegee intermediates.
format	article
author	Bo Long Junwei Lucas Bao Donald G. Truhlar
author_facet	Bo Long Junwei Lucas Bao Donald G. Truhlar
author_sort	Bo Long
title	Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry
title_short	Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry
title_full	Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry
title_fullStr	Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry
title_full_unstemmed	Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry
title_sort	rapid unimolecular reaction of stabilized criegee intermediates and implications for atmospheric chemistry
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/2884648f595e4ddd8db9b61c5cd7842e
work_keys_str_mv	AT bolong rapidunimolecularreactionofstabilizedcriegeeintermediatesandimplicationsforatmosphericchemistry AT junweilucasbao rapidunimolecularreactionofstabilizedcriegeeintermediatesandimplicationsforatmosphericchemistry AT donaldgtruhlar rapidunimolecularreactionofstabilizedcriegeeintermediatesandimplicationsforatmosphericchemistry
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Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry

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