Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry

Criegee intermediates have received much attention in atmospheric chemistry because of their importance in ozonolysis mechanisms. Here, using quantum mechanical kinetics, the authors reveal an unexpectedly fast mechanistic pathway for unimolecular reactions of large stabilized Criegee intermediates.

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Detalles Bibliográficos
Autores principales: Bo Long, Junwei Lucas Bao, Donald G. Truhlar
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
Materias:
Q
Acceso en línea:https://doaj.org/article/2884648f595e4ddd8db9b61c5cd7842e
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