Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis

The dependence of the Cu-catalysed methanol synthesis on the structure of the Cu surface is a matter of debate. Here the authors show that activity falls for Cu and Cu-Zn particles below 8 nm and propose this is due to the absence of certain atomic configurations on the smaller particle surfaces.

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Auteurs principaux: Roy van den Berg, Gonzalo Prieto, Gerda Korpershoek, Lars I. van der Wal, Arnoldus J. van Bunningen, Susanne Lægsgaard-Jørgensen, Petra E. de Jongh, Krijn P. de Jong
Format: article
Langue:EN
Publié: Nature Portfolio 2016
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Accès en ligne:https://doaj.org/article/2e06b38b2b9e427a82e69780c10cd882
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