Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis

The dependence of the Cu-catalysed methanol synthesis on the structure of the Cu surface is a matter of debate. Here the authors show that activity falls for Cu and Cu-Zn particles below 8 nm and propose this is due to the absence of certain atomic configurations on the smaller particle surfaces.

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Autores principales:	Roy van den Berg, Gonzalo Prieto, Gerda Korpershoek, Lars I. van der Wal, Arnoldus J. van Bunningen, Susanne Lægsgaard-Jørgensen, Petra E. de Jongh, Krijn P. de Jong
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/2e06b38b2b9e427a82e69780c10cd882
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spelling	oai:doaj.org-article:2e06b38b2b9e427a82e69780c10cd8822021-12-02T17:31:48ZStructure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis10.1038/ncomms130572041-1723https://doaj.org/article/2e06b38b2b9e427a82e69780c10cd8822016-10-01T00:00:00Zhttps://doi.org/10.1038/ncomms13057https://doaj.org/toc/2041-1723The dependence of the Cu-catalysed methanol synthesis on the structure of the Cu surface is a matter of debate. Here the authors show that activity falls for Cu and Cu-Zn particles below 8 nm and propose this is due to the absence of certain atomic configurations on the smaller particle surfaces.Roy van den BergGonzalo PrietoGerda KorpershoekLars I. van der WalArnoldus J. van BunningenSusanne Lægsgaard-JørgensenPetra E. de JonghKrijn P. de JongNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-7 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Roy van den Berg Gonzalo Prieto Gerda Korpershoek Lars I. van der Wal Arnoldus J. van Bunningen Susanne Lægsgaard-Jørgensen Petra E. de Jongh Krijn P. de Jong Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis
description	The dependence of the Cu-catalysed methanol synthesis on the structure of the Cu surface is a matter of debate. Here the authors show that activity falls for Cu and Cu-Zn particles below 8 nm and propose this is due to the absence of certain atomic configurations on the smaller particle surfaces.
format	article
author	Roy van den Berg Gonzalo Prieto Gerda Korpershoek Lars I. van der Wal Arnoldus J. van Bunningen Susanne Lægsgaard-Jørgensen Petra E. de Jongh Krijn P. de Jong
author_facet	Roy van den Berg Gonzalo Prieto Gerda Korpershoek Lars I. van der Wal Arnoldus J. van Bunningen Susanne Lægsgaard-Jørgensen Petra E. de Jongh Krijn P. de Jong
author_sort	Roy van den Berg
title	Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis
title_short	Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis
title_full	Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis
title_fullStr	Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis
title_full_unstemmed	Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis
title_sort	structure sensitivity of cu and cuzn catalysts relevant to industrial methanol synthesis
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/2e06b38b2b9e427a82e69780c10cd882
work_keys_str_mv	AT royvandenberg structuresensitivityofcuandcuzncatalystsrelevanttoindustrialmethanolsynthesis AT gonzaloprieto structuresensitivityofcuandcuzncatalystsrelevanttoindustrialmethanolsynthesis AT gerdakorpershoek structuresensitivityofcuandcuzncatalystsrelevanttoindustrialmethanolsynthesis AT larsivanderwal structuresensitivityofcuandcuzncatalystsrelevanttoindustrialmethanolsynthesis AT arnoldusjvanbunningen structuresensitivityofcuandcuzncatalystsrelevanttoindustrialmethanolsynthesis AT susannelægsgaardjørgensen structuresensitivityofcuandcuzncatalystsrelevanttoindustrialmethanolsynthesis AT petraedejongh structuresensitivityofcuandcuzncatalystsrelevanttoindustrialmethanolsynthesis AT krijnpdejong structuresensitivityofcuandcuzncatalystsrelevanttoindustrialmethanolsynthesis
_version_	1718380480919764992

Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis

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