Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations

The electrochemical behaviour of redox-active metal cations foremost depends on the metal centre’s inner-sphere coordination environment. Here the authors show that electrolyte cations unexpectedly stabilize higher-oxidation-state neptunium dioxocations in water through extended-coordination sphere...

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Autores principales: Shanna L. Estes, Baofu Qiao, Geng Bang Jin
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/3308ca4d4e8544f0907d71fa820c2c31
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