Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations

The electrochemical behaviour of redox-active metal cations foremost depends on the metal centre’s inner-sphere coordination environment. Here the authors show that electrolyte cations unexpectedly stabilize higher-oxidation-state neptunium dioxocations in water through extended-coordination sphere...

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Autores principales:	Shanna L. Estes, Baofu Qiao, Geng Bang Jin
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/3308ca4d4e8544f0907d71fa820c2c31
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spelling	oai:doaj.org-article:3308ca4d4e8544f0907d71fa820c2c312021-12-02T16:57:11ZIon association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations10.1038/s41467-018-07982-52041-1723https://doaj.org/article/3308ca4d4e8544f0907d71fa820c2c312019-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07982-5https://doaj.org/toc/2041-1723The electrochemical behaviour of redox-active metal cations foremost depends on the metal centre’s inner-sphere coordination environment. Here the authors show that electrolyte cations unexpectedly stabilize higher-oxidation-state neptunium dioxocations in water through extended-coordination sphere interactions.Shanna L. EstesBaofu QiaoGeng Bang JinNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Shanna L. Estes Baofu Qiao Geng Bang Jin Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations
description	The electrochemical behaviour of redox-active metal cations foremost depends on the metal centre’s inner-sphere coordination environment. Here the authors show that electrolyte cations unexpectedly stabilize higher-oxidation-state neptunium dioxocations in water through extended-coordination sphere interactions.
format	article
author	Shanna L. Estes Baofu Qiao Geng Bang Jin
author_facet	Shanna L. Estes Baofu Qiao Geng Bang Jin
author_sort	Shanna L. Estes
title	Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations
title_short	Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations
title_full	Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations
title_fullStr	Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations
title_full_unstemmed	Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations
title_sort	ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/3308ca4d4e8544f0907d71fa820c2c31
work_keys_str_mv	AT shannalestes ionassociationwithtetranalkylammoniumcationsstabilizeshigheroxidationstateneptuniumdioxocations AT baofuqiao ionassociationwithtetranalkylammoniumcationsstabilizeshigheroxidationstateneptuniumdioxocations AT gengbangjin ionassociationwithtetranalkylammoniumcationsstabilizeshigheroxidationstateneptuniumdioxocations
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Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations

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