Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations
The electrochemical behaviour of redox-active metal cations foremost depends on the metal centre’s inner-sphere coordination environment. Here the authors show that electrolyte cations unexpectedly stabilize higher-oxidation-state neptunium dioxocations in water through extended-coordination sphere...
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Auteurs principaux: | Shanna L. Estes, Baofu Qiao, Geng Bang Jin |
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Format: | article |
Langue: | EN |
Publié: |
Nature Portfolio
2019
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Accès en ligne: | https://doaj.org/article/3308ca4d4e8544f0907d71fa820c2c31 |
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