Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives

The selective installation of quaternary carbon substituents on arenes is a highly challenging synthetic goal. Here, the authors report a chromium-catalyzed para-selective functionalization of benzamides with tertiary organometallic reagents under mild conditions.

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Autores principales:	Pei Liu, Changpeng Chen, Xuefeng Cong, Jinghua Tang, Xiaoming Zeng
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/36d4db8f29df4dba8e839983948971d6
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spelling	oai:doaj.org-article:36d4db8f29df4dba8e839983948971d62021-12-02T15:33:42ZChromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives10.1038/s41467-018-07069-12041-1723https://doaj.org/article/36d4db8f29df4dba8e839983948971d62018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07069-1https://doaj.org/toc/2041-1723The selective installation of quaternary carbon substituents on arenes is a highly challenging synthetic goal. Here, the authors report a chromium-catalyzed para-selective functionalization of benzamides with tertiary organometallic reagents under mild conditions.Pei LiuChangpeng ChenXuefeng CongJinghua TangXiaoming ZengNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Pei Liu Changpeng Chen Xuefeng Cong Jinghua Tang Xiaoming Zeng Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives
description	The selective installation of quaternary carbon substituents on arenes is a highly challenging synthetic goal. Here, the authors report a chromium-catalyzed para-selective functionalization of benzamides with tertiary organometallic reagents under mild conditions.
format	article
author	Pei Liu Changpeng Chen Xuefeng Cong Jinghua Tang Xiaoming Zeng
author_facet	Pei Liu Changpeng Chen Xuefeng Cong Jinghua Tang Xiaoming Zeng
author_sort	Pei Liu
title	Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives
title_short	Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives
title_full	Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives
title_fullStr	Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives
title_full_unstemmed	Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives
title_sort	chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/36d4db8f29df4dba8e839983948971d6
work_keys_str_mv	AT peiliu chromiumcatalyzedparaselectiveformationofquaternarycarboncentersbyalkylationofbenzamidederivatives AT changpengchen chromiumcatalyzedparaselectiveformationofquaternarycarboncentersbyalkylationofbenzamidederivatives AT xuefengcong chromiumcatalyzedparaselectiveformationofquaternarycarboncentersbyalkylationofbenzamidederivatives AT jinghuatang chromiumcatalyzedparaselectiveformationofquaternarycarboncentersbyalkylationofbenzamidederivatives AT xiaomingzeng chromiumcatalyzedparaselectiveformationofquaternarycarboncentersbyalkylationofbenzamidederivatives
_version_	1718387015837286400

Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives

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