Iodine-catalyzed diazo activation to access radical reactivity

Radical reactivity of diazo compounds, useful organic building blocks, is yet underexplored. Here, the authors report an iodine-catalyzed radical activation of diazo compounds affording a variety of substituted cyclopropanes, pyrroles and epoxides under either thermal- or photo-initiated conditions.

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Autores principales: Pan Li, Jingjing Zhao, Lijun Shi, Jin Wang, Xiaodong Shi, Fuwei Li
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/3d4bdc12eafd4435b303af919c20f59c
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