Iodine-catalyzed diazo activation to access radical reactivity

Iodine-catalyzed diazo activation to access radical reactivity

Radical reactivity of diazo compounds, useful organic building blocks, is yet underexplored. Here, the authors report an iodine-catalyzed radical activation of diazo compounds affording a variety of substituted cyclopropanes, pyrroles and epoxides under either thermal- or photo-initiated conditions.

Guardado en:
Detalles Bibliográficos
Autores principales: Pan Li, Jingjing Zhao, Lijun Shi, Jin Wang, Xiaodong Shi, Fuwei Li
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
Materias:
Science
Q
Acceso en línea:https://doaj.org/article/3d4bdc12eafd4435b303af919c20f59c
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:3d4bdc12eafd4435b303af919c20f59c
record_format dspace
spelling oai:doaj.org-article:3d4bdc12eafd4435b303af919c20f59c2021-12-02T14:39:28ZIodine-catalyzed diazo activation to access radical reactivity10.1038/s41467-018-04331-42041-1723https://doaj.org/article/3d4bdc12eafd4435b303af919c20f59c2018-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04331-4https://doaj.org/toc/2041-1723Radical reactivity of diazo compounds, useful organic building blocks, is yet underexplored. Here, the authors report an iodine-catalyzed radical activation of diazo compounds affording a variety of substituted cyclopropanes, pyrroles and epoxides under either thermal- or photo-initiated conditions.Pan LiJingjing ZhaoLijun ShiJin WangXiaodong ShiFuwei LiNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Pan Li
Jingjing Zhao
Lijun Shi
Jin Wang
Xiaodong Shi
Fuwei Li
Iodine-catalyzed diazo activation to access radical reactivity
description Radical reactivity of diazo compounds, useful organic building blocks, is yet underexplored. Here, the authors report an iodine-catalyzed radical activation of diazo compounds affording a variety of substituted cyclopropanes, pyrroles and epoxides under either thermal- or photo-initiated conditions.
format article
author Pan Li
Jingjing Zhao
Lijun Shi
Jin Wang
Xiaodong Shi
Fuwei Li
author_facet Pan Li
Jingjing Zhao
Lijun Shi
Jin Wang
Xiaodong Shi
Fuwei Li
author_sort Pan Li
title Iodine-catalyzed diazo activation to access radical reactivity
title_short Iodine-catalyzed diazo activation to access radical reactivity
title_full Iodine-catalyzed diazo activation to access radical reactivity
title_fullStr Iodine-catalyzed diazo activation to access radical reactivity
title_full_unstemmed Iodine-catalyzed diazo activation to access radical reactivity
title_sort iodine-catalyzed diazo activation to access radical reactivity
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/3d4bdc12eafd4435b303af919c20f59c
work_keys_str_mv AT panli iodinecatalyzeddiazoactivationtoaccessradicalreactivity
AT jingjingzhao iodinecatalyzeddiazoactivationtoaccessradicalreactivity
AT lijunshi iodinecatalyzeddiazoactivationtoaccessradicalreactivity
AT jinwang iodinecatalyzeddiazoactivationtoaccessradicalreactivity
AT xiaodongshi iodinecatalyzeddiazoactivationtoaccessradicalreactivity
AT fuweili iodinecatalyzeddiazoactivationtoaccessradicalreactivity
_version_ 1718390586082328576

Ejemplares similares