Role of hydrogen bond alternation and charge transfer states in photoactivation of the Orange Carotenoid Protein

Role of hydrogen bond alternation and charge transfer states in photoactivation of the Orange Carotenoid Protein

Yaroshevich et al. present a chemical reaction mechanism of a 35-kDa blue light-triggered photoreceptor, the Orange Carotenoid Protein (OCP). They find that photoactivation critically involves the transient formation of a protonated ketocarotenoid (oxocarbenium cation) state. This study suggests the...

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Autores principales: Igor A. Yaroshevich, Eugene G. Maksimov, Nikolai N. Sluchanko, Dmitry V. Zlenko, Alexey V. Stepanov, Ekaterina A. Slutskaya, Yury B. Slonimskiy, Viacheslav S. Botnarevskii, Alina Remeeva, Ivan Gushchin, Kirill Kovalev, Valentin I. Gordeliy, Ivan V. Shelaev, Fedor E. Gostev, Dmitry Khakhulin, Vladimir V. Poddubnyy, Timofey S. Gostev, Dmitry A. Cherepanov, Tomáš Polívka, Miroslav Kloz, Thomas Friedrich, Vladimir Z. Paschenko, Victor A. Nadtochenko, Andrew B. Rubin, Mikhail P. Kirpichnikov
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
Materias:
Biology (General)
QH301-705.5
Acceso en línea:https://doaj.org/article/40cdd7274af644f0968f4c7f7500f01e
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https://doaj.org/article/40cdd7274af644f0968f4c7f7500f01e

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