Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity

Unlike traditional chiral metal complexes, which typically contain chiral ligands, in chiral-at-metal complexes chirality originates from a stereogenic metal center bound to achiral ligands. Herein, the authors use an unsymmetric tridentate ligand to construct a Werner-type tetrahedral chiral-at-zin...

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Bibliographic Details
Main Authors: Kenichi Endo, Yuanfei Liu, Hitoshi Ube, Koichi Nagata, Mitsuhiko Shionoya
Format: article
Language:EN
Published: Nature Portfolio 2020
Subjects:
Q
Online Access:https://doaj.org/article/427f73a60f234df092d7299bc432f25a
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