Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity
Unlike traditional chiral metal complexes, which typically contain chiral ligands, in chiral-at-metal complexes chirality originates from a stereogenic metal center bound to achiral ligands. Herein, the authors use an unsymmetric tridentate ligand to construct a Werner-type tetrahedral chiral-at-zin...
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Nature Portfolio
2020
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oai:doaj.org-article:427f73a60f234df092d7299bc432f25a2021-12-02T14:16:24ZAsymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity10.1038/s41467-020-20074-72041-1723https://doaj.org/article/427f73a60f234df092d7299bc432f25a2020-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20074-7https://doaj.org/toc/2041-1723Unlike traditional chiral metal complexes, which typically contain chiral ligands, in chiral-at-metal complexes chirality originates from a stereogenic metal center bound to achiral ligands. Herein, the authors use an unsymmetric tridentate ligand to construct a Werner-type tetrahedral chiral-at-zinc complex which displays high configurational stability and catalyzes an oxa-Diels-Alder reaction with high yield and enantioselectivity.Kenichi EndoYuanfei LiuHitoshi UbeKoichi NagataMitsuhiko ShionoyaNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-7 (2020) |
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Science Q Kenichi Endo Yuanfei Liu Hitoshi Ube Koichi Nagata Mitsuhiko Shionoya Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity |
description |
Unlike traditional chiral metal complexes, which typically contain chiral ligands, in chiral-at-metal complexes chirality originates from a stereogenic metal center bound to achiral ligands. Herein, the authors use an unsymmetric tridentate ligand to construct a Werner-type tetrahedral chiral-at-zinc complex which displays high configurational stability and catalyzes an oxa-Diels-Alder reaction with high yield and enantioselectivity. |
format |
article |
author |
Kenichi Endo Yuanfei Liu Hitoshi Ube Koichi Nagata Mitsuhiko Shionoya |
author_facet |
Kenichi Endo Yuanfei Liu Hitoshi Ube Koichi Nagata Mitsuhiko Shionoya |
author_sort |
Kenichi Endo |
title |
Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity |
title_short |
Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity |
title_full |
Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity |
title_fullStr |
Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity |
title_full_unstemmed |
Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity |
title_sort |
asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity |
publisher |
Nature Portfolio |
publishDate |
2020 |
url |
https://doaj.org/article/427f73a60f234df092d7299bc432f25a |
work_keys_str_mv |
AT kenichiendo asymmetricconstructionoftetrahedralchiralzincwithhighconfigurationalstabilityandcatalyticactivity AT yuanfeiliu asymmetricconstructionoftetrahedralchiralzincwithhighconfigurationalstabilityandcatalyticactivity AT hitoshiube asymmetricconstructionoftetrahedralchiralzincwithhighconfigurationalstabilityandcatalyticactivity AT koichinagata asymmetricconstructionoftetrahedralchiralzincwithhighconfigurationalstabilityandcatalyticactivity AT mitsuhikoshionoya asymmetricconstructionoftetrahedralchiralzincwithhighconfigurationalstabilityandcatalyticactivity |
_version_ |
1718391663277113344 |