Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity

Unlike traditional chiral metal complexes, which typically contain chiral ligands, in chiral-at-metal complexes chirality originates from a stereogenic metal center bound to achiral ligands. Herein, the authors use an unsymmetric tridentate ligand to construct a Werner-type tetrahedral chiral-at-zin...

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Autores principales: Kenichi Endo, Yuanfei Liu, Hitoshi Ube, Koichi Nagata, Mitsuhiko Shionoya
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/427f73a60f234df092d7299bc432f25a
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spelling oai:doaj.org-article:427f73a60f234df092d7299bc432f25a2021-12-02T14:16:24ZAsymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity10.1038/s41467-020-20074-72041-1723https://doaj.org/article/427f73a60f234df092d7299bc432f25a2020-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20074-7https://doaj.org/toc/2041-1723Unlike traditional chiral metal complexes, which typically contain chiral ligands, in chiral-at-metal complexes chirality originates from a stereogenic metal center bound to achiral ligands. Herein, the authors use an unsymmetric tridentate ligand to construct a Werner-type tetrahedral chiral-at-zinc complex which displays high configurational stability and catalyzes an oxa-Diels-Alder reaction with high yield and enantioselectivity.Kenichi EndoYuanfei LiuHitoshi UbeKoichi NagataMitsuhiko ShionoyaNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Kenichi Endo
Yuanfei Liu
Hitoshi Ube
Koichi Nagata
Mitsuhiko Shionoya
Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity
description Unlike traditional chiral metal complexes, which typically contain chiral ligands, in chiral-at-metal complexes chirality originates from a stereogenic metal center bound to achiral ligands. Herein, the authors use an unsymmetric tridentate ligand to construct a Werner-type tetrahedral chiral-at-zinc complex which displays high configurational stability and catalyzes an oxa-Diels-Alder reaction with high yield and enantioselectivity.
format article
author Kenichi Endo
Yuanfei Liu
Hitoshi Ube
Koichi Nagata
Mitsuhiko Shionoya
author_facet Kenichi Endo
Yuanfei Liu
Hitoshi Ube
Koichi Nagata
Mitsuhiko Shionoya
author_sort Kenichi Endo
title Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity
title_short Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity
title_full Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity
title_fullStr Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity
title_full_unstemmed Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity
title_sort asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/427f73a60f234df092d7299bc432f25a
work_keys_str_mv AT kenichiendo asymmetricconstructionoftetrahedralchiralzincwithhighconfigurationalstabilityandcatalyticactivity
AT yuanfeiliu asymmetricconstructionoftetrahedralchiralzincwithhighconfigurationalstabilityandcatalyticactivity
AT hitoshiube asymmetricconstructionoftetrahedralchiralzincwithhighconfigurationalstabilityandcatalyticactivity
AT koichinagata asymmetricconstructionoftetrahedralchiralzincwithhighconfigurationalstabilityandcatalyticactivity
AT mitsuhikoshionoya asymmetricconstructionoftetrahedralchiralzincwithhighconfigurationalstabilityandcatalyticactivity
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