Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex

An essential open question in functional transition metal complexes is the relative roles of charge-transfer and metal-centered excited states. Here the authors identify the important role of metal-centered excited states in the linkage photoisomerization of a photochromic Ru-sulfoxide complex.

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Auteurs principaux: Amy A. Cordones, Jae Hyuk Lee, Kiryong Hong, Hana Cho, Komal Garg, Martial Boggio-Pasqua, Jeffrey J. Rack, Nils Huse, Robert W. Schoenlein, Tae Kyu Kim
Format: article
Langue:EN
Publié: Nature Portfolio 2018
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Accès en ligne:https://doaj.org/article/5731d4b61cda4b98bf6ab4e0e3b835b2
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Résumé:An essential open question in functional transition metal complexes is the relative roles of charge-transfer and metal-centered excited states. Here the authors identify the important role of metal-centered excited states in the linkage photoisomerization of a photochromic Ru-sulfoxide complex.