Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex

In enantioselective catalysis, electron donor–acceptor (EDA) complexes are usually photochemically activated in an intermolecular fashion. Here, the authors report the stereoselective conjugate addition to β-substituted cyclic enones proceeding without external photoredox catalysts via an intramolec...

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Autores principales: Zhong-Yan Cao, Tamal Ghosh, Paolo Melchiorre
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/5c44d18050af4171ab84e769ffbff73e
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