Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex

In enantioselective catalysis, electron donor–acceptor (EDA) complexes are usually photochemically activated in an intermolecular fashion. Here, the authors report the stereoselective conjugate addition to β-substituted cyclic enones proceeding without external photoredox catalysts via an intramolec...

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Autores principales:	Zhong-Yan Cao, Tamal Ghosh, Paolo Melchiorre
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5c44d18050af4171ab84e769ffbff73e
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spelling	oai:doaj.org-article:5c44d18050af4171ab84e769ffbff73e2021-12-02T14:39:08ZEnantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex10.1038/s41467-018-05375-22041-1723https://doaj.org/article/5c44d18050af4171ab84e769ffbff73e2018-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05375-2https://doaj.org/toc/2041-1723In enantioselective catalysis, electron donor–acceptor (EDA) complexes are usually photochemically activated in an intermolecular fashion. Here, the authors report the stereoselective conjugate addition to β-substituted cyclic enones proceeding without external photoredox catalysts via an intramolecular EDA complex.Zhong-Yan CaoTamal GhoshPaolo MelchiorreNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Zhong-Yan Cao Tamal Ghosh Paolo Melchiorre Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex
description	In enantioselective catalysis, electron donor–acceptor (EDA) complexes are usually photochemically activated in an intermolecular fashion. Here, the authors report the stereoselective conjugate addition to β-substituted cyclic enones proceeding without external photoredox catalysts via an intramolecular EDA complex.
format	article
author	Zhong-Yan Cao Tamal Ghosh Paolo Melchiorre
author_facet	Zhong-Yan Cao Tamal Ghosh Paolo Melchiorre
author_sort	Zhong-Yan Cao
title	Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex
title_short	Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex
title_full	Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex
title_fullStr	Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex
title_full_unstemmed	Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex
title_sort	enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based eda complex
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/5c44d18050af4171ab84e769ffbff73e
work_keys_str_mv	AT zhongyancao enantioselectiveradicalconjugateadditionsdrivenbyaphotoactiveintramoleculariminiumionbasededacomplex AT tamalghosh enantioselectiveradicalconjugateadditionsdrivenbyaphotoactiveintramoleculariminiumionbasededacomplex AT paolomelchiorre enantioselectiveradicalconjugateadditionsdrivenbyaphotoactiveintramoleculariminiumionbasededacomplex
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Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex

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