Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex
In enantioselective catalysis, electron donor–acceptor (EDA) complexes are usually photochemically activated in an intermolecular fashion. Here, the authors report the stereoselective conjugate addition to β-substituted cyclic enones proceeding without external photoredox catalysts via an intramolec...
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Autores principales: | Zhong-Yan Cao, Tamal Ghosh, Paolo Melchiorre |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2018
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Materias: | |
Acceso en línea: | https://doaj.org/article/5c44d18050af4171ab84e769ffbff73e |
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