Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation

Peroxomolybdates can be used as catalysts, but to date have not been employed in catalytic asymmetric transformations. Here the authors report that peroxomolybdates with a chiral bisguanidinium salts are active catalysts for asymmetric sulfoxidation, and furthermore identify the catalytic species.

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Autores principales: Lili Zong, Chao Wang, Adhitya Mangala Putra Moeljadi, Xinyi Ye, Rakesh Ganguly, Yongxin Li, Hajime Hirao, Choon-Hong Tan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/7263dde9d232456f9d1d5f5a02f03398
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