Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation

Peroxomolybdates can be used as catalysts, but to date have not been employed in catalytic asymmetric transformations. Here the authors report that peroxomolybdates with a chiral bisguanidinium salts are active catalysts for asymmetric sulfoxidation, and furthermore identify the catalytic species.

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Autores principales:	Lili Zong, Chao Wang, Adhitya Mangala Putra Moeljadi, Xinyi Ye, Rakesh Ganguly, Yongxin Li, Hajime Hirao, Choon-Hong Tan
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/7263dde9d232456f9d1d5f5a02f03398
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spelling	oai:doaj.org-article:7263dde9d232456f9d1d5f5a02f033982021-12-02T17:32:38ZBisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation10.1038/ncomms134552041-1723https://doaj.org/article/7263dde9d232456f9d1d5f5a02f033982016-11-01T00:00:00Zhttps://doi.org/10.1038/ncomms13455https://doaj.org/toc/2041-1723Peroxomolybdates can be used as catalysts, but to date have not been employed in catalytic asymmetric transformations. Here the authors report that peroxomolybdates with a chiral bisguanidinium salts are active catalysts for asymmetric sulfoxidation, and furthermore identify the catalytic species.Lili ZongChao WangAdhitya Mangala Putra MoeljadiXinyi YeRakesh GangulyYongxin LiHajime HiraoChoon-Hong TanNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-7 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Lili Zong Chao Wang Adhitya Mangala Putra Moeljadi Xinyi Ye Rakesh Ganguly Yongxin Li Hajime Hirao Choon-Hong Tan Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation
description	Peroxomolybdates can be used as catalysts, but to date have not been employed in catalytic asymmetric transformations. Here the authors report that peroxomolybdates with a chiral bisguanidinium salts are active catalysts for asymmetric sulfoxidation, and furthermore identify the catalytic species.
format	article
author	Lili Zong Chao Wang Adhitya Mangala Putra Moeljadi Xinyi Ye Rakesh Ganguly Yongxin Li Hajime Hirao Choon-Hong Tan
author_facet	Lili Zong Chao Wang Adhitya Mangala Putra Moeljadi Xinyi Ye Rakesh Ganguly Yongxin Li Hajime Hirao Choon-Hong Tan
author_sort	Lili Zong
title	Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation
title_short	Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation
title_full	Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation
title_fullStr	Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation
title_full_unstemmed	Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation
title_sort	bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/7263dde9d232456f9d1d5f5a02f03398
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Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation

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