Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation

Peroxomolybdates can be used as catalysts, but to date have not been employed in catalytic asymmetric transformations. Here the authors report that peroxomolybdates with a chiral bisguanidinium salts are active catalysts for asymmetric sulfoxidation, and furthermore identify the catalytic species.

Saved in:
Bibliographic Details
Main Authors: Lili Zong, Chao Wang, Adhitya Mangala Putra Moeljadi, Xinyi Ye, Rakesh Ganguly, Yongxin Li, Hajime Hirao, Choon-Hong Tan
Format: article
Language:EN
Published: Nature Portfolio 2016
Subjects:
Q
Online Access:https://doaj.org/article/7263dde9d232456f9d1d5f5a02f03398
Tags: Add Tag
No Tags, Be the first to tag this record!