π covalency in the halogen bond

Current models of halogen bonding describe the σ-symmetric component of this interaction but do not contemplate the possibility of π-covalency. Here the authors provide experimental and computational evidence of π-covalency in halogen bonds involving radical cation halogen bond donors.

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Detalles Bibliográficos
Autores principales: Cameron W. Kellett, Pierre Kennepohl, Curtis P. Berlinguette
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
Materias:
Q
Acceso en línea:https://doaj.org/article/77c0b6e8dae3433685f37ba80d779f87
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