π covalency in the halogen bond

Current models of halogen bonding describe the σ-symmetric component of this interaction but do not contemplate the possibility of π-covalency. Here the authors provide experimental and computational evidence of π-covalency in halogen bonds involving radical cation halogen bond donors.

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Detalles Bibliográficos
Autores principales:	Cameron W. Kellett, Pierre Kennepohl, Curtis P. Berlinguette
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/77c0b6e8dae3433685f37ba80d779f87
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spelling	oai:doaj.org-article:77c0b6e8dae3433685f37ba80d779f872021-12-02T16:32:09Zπ covalency in the halogen bond10.1038/s41467-020-17122-72041-1723https://doaj.org/article/77c0b6e8dae3433685f37ba80d779f872020-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-17122-7https://doaj.org/toc/2041-1723Current models of halogen bonding describe the σ-symmetric component of this interaction but do not contemplate the possibility of π-covalency. Here the authors provide experimental and computational evidence of π-covalency in halogen bonds involving radical cation halogen bond donors.Cameron W. KellettPierre KennepohlCurtis P. BerlinguetteNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Cameron W. Kellett Pierre Kennepohl Curtis P. Berlinguette π covalency in the halogen bond
description	Current models of halogen bonding describe the σ-symmetric component of this interaction but do not contemplate the possibility of π-covalency. Here the authors provide experimental and computational evidence of π-covalency in halogen bonds involving radical cation halogen bond donors.
format	article
author	Cameron W. Kellett Pierre Kennepohl Curtis P. Berlinguette
author_facet	Cameron W. Kellett Pierre Kennepohl Curtis P. Berlinguette
author_sort	Cameron W. Kellett
title	π covalency in the halogen bond
title_short	π covalency in the halogen bond
title_full	π covalency in the halogen bond
title_fullStr	π covalency in the halogen bond
title_full_unstemmed	π covalency in the halogen bond
title_sort	π covalency in the halogen bond
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/77c0b6e8dae3433685f37ba80d779f87
work_keys_str_mv	AT cameronwkellett pcovalencyinthehalogenbond AT pierrekennepohl pcovalencyinthehalogenbond AT curtispberlinguette pcovalencyinthehalogenbond
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π covalency in the halogen bond

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