π covalency in the halogen bond
Current models of halogen bonding describe the σ-symmetric component of this interaction but do not contemplate the possibility of π-covalency. Here the authors provide experimental and computational evidence of π-covalency in halogen bonds involving radical cation halogen bond donors.
Guardado en:
Autores principales: | Cameron W. Kellett, Pierre Kennepohl, Curtis P. Berlinguette |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2020
|
Materias: | |
Acceso en línea: | https://doaj.org/article/77c0b6e8dae3433685f37ba80d779f87 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Spectroscopic detection of halogen bonding resolves dye regeneration in the dye-sensitized solar cell
por: Fraser G. L. Parlane, et al.
Publicado: (2017) -
Surface-controlled reversal of the selectivity of halogen bonds
por: Jalmar Tschakert, et al.
Publicado: (2020) -
Halogen bonding as a supramolecular dynamics catalyst
por: Patrick M. J. Szell, et al.
Publicado: (2019) -
The halogen bond with isocyano carbon reduces isocyanide odor
por: Alexander S. Mikherdov, et al.
Publicado: (2020) -
Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors
por: Katarina Lisac, et al.
Publicado: (2019)