Enantioselective synthesis of tertiary boronic esters through catalytic asymmetric reversed hydroboration

The development of conjugate boryl addition to α,β-unsaturated amide has been hampered by the intrinsic low electrophilicity of the amide group. Here the authors show a catalytic asymmetric synthesis of enantioenriched tertiary boronic esters through hydroboration of β,β-disubstituted α,β-unsaturate...

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Autores principales: Tao-Tao Gao, Hou-Xiang Lu, Peng-Chao Gao, Bi-Jie Li
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/79062422f6d14c12871cc6a57055e2f7
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