Enantioselective synthesis of tertiary boronic esters through catalytic asymmetric reversed hydroboration
The development of conjugate boryl addition to α,β-unsaturated amide has been hampered by the intrinsic low electrophilicity of the amide group. Here the authors show a catalytic asymmetric synthesis of enantioenriched tertiary boronic esters through hydroboration of β,β-disubstituted α,β-unsaturate...
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Autores principales: | Tao-Tao Gao, Hou-Xiang Lu, Peng-Chao Gao, Bi-Jie Li |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2021
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Materias: | |
Acceso en línea: | https://doaj.org/article/79062422f6d14c12871cc6a57055e2f7 |
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