Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids

Palladium catalysed C-H functionalization ofsp3carbons typically requires the installation and subsequent removal of a temporary directing group. Here the authors report a method allowing C-H functionalization in carboxylic acids in which the carboxylate acts as a directing group.

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Autores principales:	Yan Zhu, Xiaolan Chen, Chunchen Yuan, Guobao Li, Jingyu Zhang, Yingsheng Zhao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/79d36e5bbcad49988d35ee9fadc52393
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spelling	oai:doaj.org-article:79d36e5bbcad49988d35ee9fadc523932021-12-02T17:06:23ZPd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids10.1038/ncomms149042041-1723https://doaj.org/article/79d36e5bbcad49988d35ee9fadc523932017-04-01T00:00:00Zhttps://doi.org/10.1038/ncomms14904https://doaj.org/toc/2041-1723Palladium catalysed C-H functionalization ofsp3carbons typically requires the installation and subsequent removal of a temporary directing group. Here the authors report a method allowing C-H functionalization in carboxylic acids in which the carboxylate acts as a directing group.Yan ZhuXiaolan ChenChunchen YuanGuobao LiJingyu ZhangYingsheng ZhaoNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yan Zhu Xiaolan Chen Chunchen Yuan Guobao Li Jingyu Zhang Yingsheng Zhao Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids
description	Palladium catalysed C-H functionalization ofsp3carbons typically requires the installation and subsequent removal of a temporary directing group. Here the authors report a method allowing C-H functionalization in carboxylic acids in which the carboxylate acts as a directing group.
format	article
author	Yan Zhu Xiaolan Chen Chunchen Yuan Guobao Li Jingyu Zhang Yingsheng Zhao
author_facet	Yan Zhu Xiaolan Chen Chunchen Yuan Guobao Li Jingyu Zhang Yingsheng Zhao
author_sort	Yan Zhu
title	Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids
title_short	Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids
title_full	Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids
title_fullStr	Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids
title_full_unstemmed	Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids
title_sort	pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/79d36e5bbcad49988d35ee9fadc52393
work_keys_str_mv	AT yanzhu pdcatalysedligandenabledcarboxylatedirectedhighlyregioselectivearylationofaliphaticacids AT xiaolanchen pdcatalysedligandenabledcarboxylatedirectedhighlyregioselectivearylationofaliphaticacids AT chunchenyuan pdcatalysedligandenabledcarboxylatedirectedhighlyregioselectivearylationofaliphaticacids AT guobaoli pdcatalysedligandenabledcarboxylatedirectedhighlyregioselectivearylationofaliphaticacids AT jingyuzhang pdcatalysedligandenabledcarboxylatedirectedhighlyregioselectivearylationofaliphaticacids AT yingshengzhao pdcatalysedligandenabledcarboxylatedirectedhighlyregioselectivearylationofaliphaticacids
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Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids

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