Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis

Controlling the partial reduction of quinolines is challenging, given the competing overreduction to tetrahydroquinolines. Here, the authors report a cobalt-amido cooperative catalyst for the selective, partial transfer hydrogenation of quinolines to 1,2-dihydroquinolines with H3N·BH3 as reductant.

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Autores principales: Maofu Pang, Jia-Yi Chen, Shengjie Zhang, Rong-Zhen Liao, Chen-Ho Tung, Wenguang Wang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/7eff26af02194df48e1855fa3c34cd53
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