Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis

Controlling the partial reduction of quinolines is challenging, given the competing overreduction to tetrahydroquinolines. Here, the authors report a cobalt-amido cooperative catalyst for the selective, partial transfer hydrogenation of quinolines to 1,2-dihydroquinolines with H3N·BH3 as reductant.

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Autores principales:	Maofu Pang, Jia-Yi Chen, Shengjie Zhang, Rong-Zhen Liao, Chen-Ho Tung, Wenguang Wang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/7eff26af02194df48e1855fa3c34cd53
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spelling	oai:doaj.org-article:7eff26af02194df48e1855fa3c34cd532021-12-02T17:32:59ZControlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis10.1038/s41467-020-15118-x2041-1723https://doaj.org/article/7eff26af02194df48e1855fa3c34cd532020-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-15118-xhttps://doaj.org/toc/2041-1723Controlling the partial reduction of quinolines is challenging, given the competing overreduction to tetrahydroquinolines. Here, the authors report a cobalt-amido cooperative catalyst for the selective, partial transfer hydrogenation of quinolines to 1,2-dihydroquinolines with H3N·BH3 as reductant.Maofu PangJia-Yi ChenShengjie ZhangRong-Zhen LiaoChen-Ho TungWenguang WangNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Maofu Pang Jia-Yi Chen Shengjie Zhang Rong-Zhen Liao Chen-Ho Tung Wenguang Wang Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis
description	Controlling the partial reduction of quinolines is challenging, given the competing overreduction to tetrahydroquinolines. Here, the authors report a cobalt-amido cooperative catalyst for the selective, partial transfer hydrogenation of quinolines to 1,2-dihydroquinolines with H3N·BH3 as reductant.
format	article
author	Maofu Pang Jia-Yi Chen Shengjie Zhang Rong-Zhen Liao Chen-Ho Tung Wenguang Wang
author_facet	Maofu Pang Jia-Yi Chen Shengjie Zhang Rong-Zhen Liao Chen-Ho Tung Wenguang Wang
author_sort	Maofu Pang
title	Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis
title_short	Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis
title_full	Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis
title_fullStr	Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis
title_full_unstemmed	Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis
title_sort	controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/7eff26af02194df48e1855fa3c34cd53
work_keys_str_mv	AT maofupang controlledpartialtransferhydrogenationofquinolinesbycobaltamidocooperativecatalysis AT jiayichen controlledpartialtransferhydrogenationofquinolinesbycobaltamidocooperativecatalysis AT shengjiezhang controlledpartialtransferhydrogenationofquinolinesbycobaltamidocooperativecatalysis AT rongzhenliao controlledpartialtransferhydrogenationofquinolinesbycobaltamidocooperativecatalysis AT chenhotung controlledpartialtransferhydrogenationofquinolinesbycobaltamidocooperativecatalysis AT wenguangwang controlledpartialtransferhydrogenationofquinolinesbycobaltamidocooperativecatalysis
_version_	1718380131065528320

Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis

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