Design and application of α-ketothioesters as 1,2-dicarbonyl-forming reagents

Conventionally, 1,2-dicarbonyl compounds are prepared via α-keto acyl chlorides. Here, the authors report a metal-free synthesis of α-ketothioester reagents via the combination of an α-hydroxyl ketone, elemental sulfur and a benzyl halide, which are used for N- or C-dicarbonyl bond formation.

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Detalles Bibliográficos
Autores principales: Ming Wang, Zhihong Dai, Xuefeng Jiang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/878544c6eb8c4e43a2d54ddad2779b72
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