The limits of precision monomer placement in chain growth polymerization

Chemists increasingly seek to control monomer sequencing in aperiodic copolymers. Here, the authors show that the statistical nature of chain growth strongly limits the achievable control, and establish parameters for polymer design that balance precise control with simplicity of synthesis.

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Auteurs principaux: Guillaume Gody, Per B. Zetterlund, Sébastien Perrier, Simon Harrisson
Format: article
Langue:EN
Publié: Nature Portfolio 2016
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Accès en ligne:https://doaj.org/article/8820e8cee1a843e9b9cfed54dfa86e62
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