The limits of precision monomer placement in chain growth polymerization

Chemists increasingly seek to control monomer sequencing in aperiodic copolymers. Here, the authors show that the statistical nature of chain growth strongly limits the achievable control, and establish parameters for polymer design that balance precise control with simplicity of synthesis.

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Auteurs principaux: Guillaume Gody, Per B. Zetterlund, Sébastien Perrier, Simon Harrisson
Format: article
Langue:EN
Publié: Nature Portfolio 2016
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Accès en ligne:https://doaj.org/article/8820e8cee1a843e9b9cfed54dfa86e62
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spelling oai:doaj.org-article:8820e8cee1a843e9b9cfed54dfa86e622021-12-02T16:49:42ZThe limits of precision monomer placement in chain growth polymerization10.1038/ncomms105142041-1723https://doaj.org/article/8820e8cee1a843e9b9cfed54dfa86e622016-02-01T00:00:00Zhttps://doi.org/10.1038/ncomms10514https://doaj.org/toc/2041-1723Chemists increasingly seek to control monomer sequencing in aperiodic copolymers. Here, the authors show that the statistical nature of chain growth strongly limits the achievable control, and establish parameters for polymer design that balance precise control with simplicity of synthesis.Guillaume GodyPer B. ZetterlundSébastien PerrierSimon HarrissonNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Guillaume Gody
Per B. Zetterlund
Sébastien Perrier
Simon Harrisson
The limits of precision monomer placement in chain growth polymerization
description Chemists increasingly seek to control monomer sequencing in aperiodic copolymers. Here, the authors show that the statistical nature of chain growth strongly limits the achievable control, and establish parameters for polymer design that balance precise control with simplicity of synthesis.
format article
author Guillaume Gody
Per B. Zetterlund
Sébastien Perrier
Simon Harrisson
author_facet Guillaume Gody
Per B. Zetterlund
Sébastien Perrier
Simon Harrisson
author_sort Guillaume Gody
title The limits of precision monomer placement in chain growth polymerization
title_short The limits of precision monomer placement in chain growth polymerization
title_full The limits of precision monomer placement in chain growth polymerization
title_fullStr The limits of precision monomer placement in chain growth polymerization
title_full_unstemmed The limits of precision monomer placement in chain growth polymerization
title_sort limits of precision monomer placement in chain growth polymerization
publisher Nature Portfolio
publishDate 2016
url https://doaj.org/article/8820e8cee1a843e9b9cfed54dfa86e62
work_keys_str_mv AT guillaumegody thelimitsofprecisionmonomerplacementinchaingrowthpolymerization
AT perbzetterlund thelimitsofprecisionmonomerplacementinchaingrowthpolymerization
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AT simonharrisson thelimitsofprecisionmonomerplacementinchaingrowthpolymerization
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AT perbzetterlund limitsofprecisionmonomerplacementinchaingrowthpolymerization
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