The limits of precision monomer placement in chain growth polymerization
Chemists increasingly seek to control monomer sequencing in aperiodic copolymers. Here, the authors show that the statistical nature of chain growth strongly limits the achievable control, and establish parameters for polymer design that balance precise control with simplicity of synthesis.
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Nature Portfolio
2016
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oai:doaj.org-article:8820e8cee1a843e9b9cfed54dfa86e622021-12-02T16:49:42ZThe limits of precision monomer placement in chain growth polymerization10.1038/ncomms105142041-1723https://doaj.org/article/8820e8cee1a843e9b9cfed54dfa86e622016-02-01T00:00:00Zhttps://doi.org/10.1038/ncomms10514https://doaj.org/toc/2041-1723Chemists increasingly seek to control monomer sequencing in aperiodic copolymers. Here, the authors show that the statistical nature of chain growth strongly limits the achievable control, and establish parameters for polymer design that balance precise control with simplicity of synthesis.Guillaume GodyPer B. ZetterlundSébastien PerrierSimon HarrissonNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016) |
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Science Q Guillaume Gody Per B. Zetterlund Sébastien Perrier Simon Harrisson The limits of precision monomer placement in chain growth polymerization |
description |
Chemists increasingly seek to control monomer sequencing in aperiodic copolymers. Here, the authors show that the statistical nature of chain growth strongly limits the achievable control, and establish parameters for polymer design that balance precise control with simplicity of synthesis. |
format |
article |
author |
Guillaume Gody Per B. Zetterlund Sébastien Perrier Simon Harrisson |
author_facet |
Guillaume Gody Per B. Zetterlund Sébastien Perrier Simon Harrisson |
author_sort |
Guillaume Gody |
title |
The limits of precision monomer placement in chain growth polymerization |
title_short |
The limits of precision monomer placement in chain growth polymerization |
title_full |
The limits of precision monomer placement in chain growth polymerization |
title_fullStr |
The limits of precision monomer placement in chain growth polymerization |
title_full_unstemmed |
The limits of precision monomer placement in chain growth polymerization |
title_sort |
limits of precision monomer placement in chain growth polymerization |
publisher |
Nature Portfolio |
publishDate |
2016 |
url |
https://doaj.org/article/8820e8cee1a843e9b9cfed54dfa86e62 |
work_keys_str_mv |
AT guillaumegody thelimitsofprecisionmonomerplacementinchaingrowthpolymerization AT perbzetterlund thelimitsofprecisionmonomerplacementinchaingrowthpolymerization AT sebastienperrier thelimitsofprecisionmonomerplacementinchaingrowthpolymerization AT simonharrisson thelimitsofprecisionmonomerplacementinchaingrowthpolymerization AT guillaumegody limitsofprecisionmonomerplacementinchaingrowthpolymerization AT perbzetterlund limitsofprecisionmonomerplacementinchaingrowthpolymerization AT sebastienperrier limitsofprecisionmonomerplacementinchaingrowthpolymerization AT simonharrisson limitsofprecisionmonomerplacementinchaingrowthpolymerization |
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1718383226756530176 |