Dearomative 1,4-difunctionalization of naphthalenes via palladium-catalyzed tandem Heck/Suzuki coupling reaction

Naphthalene is a challenging arene towards transition-metal-catalyzed dearomative difunctionalization. Here, the authors show that naphthalene may act as a masked conjugated diene in palladium-catalyzed dearomative 1,4-diarylation or 1,4-vinylarylation via a tandem Heck/Suzuki sequence.

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Autores principales:	Bo Zhou, Hongliang Wang, Zhong-Yan Cao, Jia-Wen Zhu, Ren-Xiao Liang, Xin Hong, Yi-Xia Jia
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/89129853682a4f80a7f326b2d5c8704f
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spelling	oai:doaj.org-article:89129853682a4f80a7f326b2d5c8704f2021-12-02T16:38:27ZDearomative 1,4-difunctionalization of naphthalenes via palladium-catalyzed tandem Heck/Suzuki coupling reaction10.1038/s41467-020-18137-w2041-1723https://doaj.org/article/89129853682a4f80a7f326b2d5c8704f2020-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-18137-whttps://doaj.org/toc/2041-1723Naphthalene is a challenging arene towards transition-metal-catalyzed dearomative difunctionalization. Here, the authors show that naphthalene may act as a masked conjugated diene in palladium-catalyzed dearomative 1,4-diarylation or 1,4-vinylarylation via a tandem Heck/Suzuki sequence.Bo ZhouHongliang WangZhong-Yan CaoJia-Wen ZhuRen-Xiao LiangXin HongYi-Xia JiaNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Bo Zhou Hongliang Wang Zhong-Yan Cao Jia-Wen Zhu Ren-Xiao Liang Xin Hong Yi-Xia Jia Dearomative 1,4-difunctionalization of naphthalenes via palladium-catalyzed tandem Heck/Suzuki coupling reaction
description	Naphthalene is a challenging arene towards transition-metal-catalyzed dearomative difunctionalization. Here, the authors show that naphthalene may act as a masked conjugated diene in palladium-catalyzed dearomative 1,4-diarylation or 1,4-vinylarylation via a tandem Heck/Suzuki sequence.
format	article
author	Bo Zhou Hongliang Wang Zhong-Yan Cao Jia-Wen Zhu Ren-Xiao Liang Xin Hong Yi-Xia Jia
author_facet	Bo Zhou Hongliang Wang Zhong-Yan Cao Jia-Wen Zhu Ren-Xiao Liang Xin Hong Yi-Xia Jia
author_sort	Bo Zhou
title	Dearomative 1,4-difunctionalization of naphthalenes via palladium-catalyzed tandem Heck/Suzuki coupling reaction
title_short	Dearomative 1,4-difunctionalization of naphthalenes via palladium-catalyzed tandem Heck/Suzuki coupling reaction
title_full	Dearomative 1,4-difunctionalization of naphthalenes via palladium-catalyzed tandem Heck/Suzuki coupling reaction
title_fullStr	Dearomative 1,4-difunctionalization of naphthalenes via palladium-catalyzed tandem Heck/Suzuki coupling reaction
title_full_unstemmed	Dearomative 1,4-difunctionalization of naphthalenes via palladium-catalyzed tandem Heck/Suzuki coupling reaction
title_sort	dearomative 1,4-difunctionalization of naphthalenes via palladium-catalyzed tandem heck/suzuki coupling reaction
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/89129853682a4f80a7f326b2d5c8704f
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Dearomative 1,4-difunctionalization of naphthalenes via palladium-catalyzed tandem Heck/Suzuki coupling reaction

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