Annealing Studies of Copper Indium Oxide (Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>) Thin Films Prepared by RF Magnetron Sputtering

Copper indium oxide (Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>) thin films were deposited by the RF magnetron sputtering technique using a Cu<sub>2</sub>O:In<sub>2</sub>O<sub>3</sub> target. The films were deposited on glass and...

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Autores principales: Giji Skaria, Ashwin Kumar Saikumar, Akshaya D. Shivprasad, Kalpathy B. Sundaram
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Lenguaje:EN
Publicado: MDPI AG 2021
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XRD
Acceso en línea:https://doaj.org/article/8de0c8eb5ee8471fa6b48f02c8cb33c0
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spelling oai:doaj.org-article:8de0c8eb5ee8471fa6b48f02c8cb33c02021-11-25T17:15:37ZAnnealing Studies of Copper Indium Oxide (Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>) Thin Films Prepared by RF Magnetron Sputtering10.3390/coatings111112902079-6412https://doaj.org/article/8de0c8eb5ee8471fa6b48f02c8cb33c02021-10-01T00:00:00Zhttps://www.mdpi.com/2079-6412/11/11/1290https://doaj.org/toc/2079-6412Copper indium oxide (Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>) thin films were deposited by the RF magnetron sputtering technique using a Cu<sub>2</sub>O:In<sub>2</sub>O<sub>3</sub> target. The films were deposited on glass and quartz substrates at room temperature. The films were subsequently annealed at temperatures ranging from 100 to 900 °C in an O<sub>2</sub> atmosphere. The X-ray diffraction (XRD) analysis performed on the samples identified the presence of Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub> phases along with CuInO<sub>2</sub> or In<sub>2</sub>O<sub>3</sub> for the films annealed above 500 °C. An increase in grain size was identified with the increase in annealing temperatures from the XRD analysis. The grain sizes were calculated to vary between 10 and 27 nm in films annealed between 500 and 900 °C. A morphological study performed using SEM further confirmed the crystallization and the grain growth with increasing annealing temperatures. All films displayed high optical transmission of more than 70% in the wavelength region of 500–800 nm. Optical studies carried out on the films indicated a small bandgap change in the range of 3.4–3.6 eV during annealing.Giji SkariaAshwin Kumar SaikumarAkshaya D. ShivprasadKalpathy B. SundaramMDPI AGarticleCu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>RF sputteringannealing studiesoptical characteristicsXRDmorphology studiesEngineering (General). Civil engineering (General)TA1-2040ENCoatings, Vol 11, Iss 1290, p 1290 (2021)
institution DOAJ
collection DOAJ
language EN
topic Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>
RF sputtering
annealing studies
optical characteristics
XRD
morphology studies
Engineering (General). Civil engineering (General)
TA1-2040
spellingShingle Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>
RF sputtering
annealing studies
optical characteristics
XRD
morphology studies
Engineering (General). Civil engineering (General)
TA1-2040
Giji Skaria
Ashwin Kumar Saikumar
Akshaya D. Shivprasad
Kalpathy B. Sundaram
Annealing Studies of Copper Indium Oxide (Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>) Thin Films Prepared by RF Magnetron Sputtering
description Copper indium oxide (Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>) thin films were deposited by the RF magnetron sputtering technique using a Cu<sub>2</sub>O:In<sub>2</sub>O<sub>3</sub> target. The films were deposited on glass and quartz substrates at room temperature. The films were subsequently annealed at temperatures ranging from 100 to 900 °C in an O<sub>2</sub> atmosphere. The X-ray diffraction (XRD) analysis performed on the samples identified the presence of Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub> phases along with CuInO<sub>2</sub> or In<sub>2</sub>O<sub>3</sub> for the films annealed above 500 °C. An increase in grain size was identified with the increase in annealing temperatures from the XRD analysis. The grain sizes were calculated to vary between 10 and 27 nm in films annealed between 500 and 900 °C. A morphological study performed using SEM further confirmed the crystallization and the grain growth with increasing annealing temperatures. All films displayed high optical transmission of more than 70% in the wavelength region of 500–800 nm. Optical studies carried out on the films indicated a small bandgap change in the range of 3.4–3.6 eV during annealing.
format article
author Giji Skaria
Ashwin Kumar Saikumar
Akshaya D. Shivprasad
Kalpathy B. Sundaram
author_facet Giji Skaria
Ashwin Kumar Saikumar
Akshaya D. Shivprasad
Kalpathy B. Sundaram
author_sort Giji Skaria
title Annealing Studies of Copper Indium Oxide (Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>) Thin Films Prepared by RF Magnetron Sputtering
title_short Annealing Studies of Copper Indium Oxide (Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>) Thin Films Prepared by RF Magnetron Sputtering
title_full Annealing Studies of Copper Indium Oxide (Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>) Thin Films Prepared by RF Magnetron Sputtering
title_fullStr Annealing Studies of Copper Indium Oxide (Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>) Thin Films Prepared by RF Magnetron Sputtering
title_full_unstemmed Annealing Studies of Copper Indium Oxide (Cu<sub>2</sub>In<sub>2</sub>O<sub>5</sub>) Thin Films Prepared by RF Magnetron Sputtering
title_sort annealing studies of copper indium oxide (cu<sub>2</sub>in<sub>2</sub>o<sub>5</sub>) thin films prepared by rf magnetron sputtering
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/8de0c8eb5ee8471fa6b48f02c8cb33c0
work_keys_str_mv AT gijiskaria annealingstudiesofcopperindiumoxidecusub2subinsub2subosub5subthinfilmspreparedbyrfmagnetronsputtering
AT ashwinkumarsaikumar annealingstudiesofcopperindiumoxidecusub2subinsub2subosub5subthinfilmspreparedbyrfmagnetronsputtering
AT akshayadshivprasad annealingstudiesofcopperindiumoxidecusub2subinsub2subosub5subthinfilmspreparedbyrfmagnetronsputtering
AT kalpathybsundaram annealingstudiesofcopperindiumoxidecusub2subinsub2subosub5subthinfilmspreparedbyrfmagnetronsputtering
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