N2 activation on a molybdenum–titanium–sulfur cluster

Nitrogenase—whose cofactor consists of a metal–sulfur cluster—catalyzes the production of NH3 from N2, but designing metal–sulfur complexes capable of promoting this conversion remains challenging. Here, the authors report on the activation of N2 by a metal–sulfur cluster containing [Mo3S4Ti] cubes,...

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Autores principales: Yasuhiro Ohki, Keisuke Uchida, Mizuki Tada, Roger E. Cramer, Takashi Ogura, Takehiro Ohta
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/92e0c066a4e642b294bc2590944c958f
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