A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling

Halogen bonding (HB) catalysis is rapidly gaining momentum, however, cases of XB activation for challenging bonds formation are rare. Here, the authors show a robust XB catalyzed 2-deoxyglycosylation with broad scope and featuring a quantum tunneling phenomenon in the proton transfer rate determinin...

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Autores principales: Chunfa Xu, V. U. Bhaskara Rao, Julia Weigen, Charles C. J. Loh
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/97b970db1d374094a4263f74f9fda1f1
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