A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling

Halogen bonding (HB) catalysis is rapidly gaining momentum, however, cases of XB activation for challenging bonds formation are rare. Here, the authors show a robust XB catalyzed 2-deoxyglycosylation with broad scope and featuring a quantum tunneling phenomenon in the proton transfer rate determinin...

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Autores principales:	Chunfa Xu, V. U. Bhaskara Rao, Julia Weigen, Charles C. J. Loh
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/97b970db1d374094a4263f74f9fda1f1
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spelling	oai:doaj.org-article:97b970db1d374094a4263f74f9fda1f12021-12-02T18:51:37ZA robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling10.1038/s41467-020-18595-22041-1723https://doaj.org/article/97b970db1d374094a4263f74f9fda1f12020-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-18595-2https://doaj.org/toc/2041-1723Halogen bonding (HB) catalysis is rapidly gaining momentum, however, cases of XB activation for challenging bonds formation are rare. Here, the authors show a robust XB catalyzed 2-deoxyglycosylation with broad scope and featuring a quantum tunneling phenomenon in the proton transfer rate determining step.Chunfa XuV. U. Bhaskara RaoJulia WeigenCharles C. J. LohNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-17 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chunfa Xu V. U. Bhaskara Rao Julia Weigen Charles C. J. Loh A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling
description	Halogen bonding (HB) catalysis is rapidly gaining momentum, however, cases of XB activation for challenging bonds formation are rare. Here, the authors show a robust XB catalyzed 2-deoxyglycosylation with broad scope and featuring a quantum tunneling phenomenon in the proton transfer rate determining step.
format	article
author	Chunfa Xu V. U. Bhaskara Rao Julia Weigen Charles C. J. Loh
author_facet	Chunfa Xu V. U. Bhaskara Rao Julia Weigen Charles C. J. Loh
author_sort	Chunfa Xu
title	A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling
title_short	A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling
title_full	A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling
title_fullStr	A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling
title_full_unstemmed	A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling
title_sort	robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/97b970db1d374094a4263f74f9fda1f1
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A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling

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