A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling
Halogen bonding (HB) catalysis is rapidly gaining momentum, however, cases of XB activation for challenging bonds formation are rare. Here, the authors show a robust XB catalyzed 2-deoxyglycosylation with broad scope and featuring a quantum tunneling phenomenon in the proton transfer rate determinin...
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Autores principales: | Chunfa Xu, V. U. Bhaskara Rao, Julia Weigen, Charles C. J. Loh |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2020
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Materias: | |
Acceso en línea: | https://doaj.org/article/97b970db1d374094a4263f74f9fda1f1 |
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