Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders

Photocatalytic nanomaterials, using only light as the source of excitation, have been developed for the breakdown of volatile organic compounds (VOCs) in air for a long time. It is a tough challenge to immobilize these powder photocatalysts and prevent their entrainment with the gas stream. Conventi...

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Auteurs principaux: Ewoud Cosaert, Cédric Wolfs, Stéphanie D. Lambert, Geraldine J. Heynderickx, Dirk Poelman
Format: article
Langue:EN
Publié: MDPI AG 2021
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Accès en ligne:https://doaj.org/article/9d35bf0d190a43cf81aa105f4e7e1cf9
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spelling oai:doaj.org-article:9d35bf0d190a43cf81aa105f4e7e1cf92021-11-11T18:33:41ZDeposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders10.3390/molecules262165841420-3049https://doaj.org/article/9d35bf0d190a43cf81aa105f4e7e1cf92021-10-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/21/6584https://doaj.org/toc/1420-3049Photocatalytic nanomaterials, using only light as the source of excitation, have been developed for the breakdown of volatile organic compounds (VOCs) in air for a long time. It is a tough challenge to immobilize these powder photocatalysts and prevent their entrainment with the gas stream. Conventional methods for making stable films typically require expensive deposition equipment and only allow the deposition of very thin layers with limited photocatalytic performance. The present work presents an alternative approach, using the combination of commercially available photocatalytic nanopowders and a polymer or inorganic sol–gel-based matrix. Analysis of the photocatalytic degradation of ethanol was studied for these layers on metallic substrates, proving a difference in photocatalytic activity for different types of stable layers. The sol–gel-based <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mi>TiO</mi><mn>2</mn></msub></semantics></math></inline-formula> layers showed an improved photocatalytic activity of the nanomaterials compared with the polymer <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mi>TiO</mi><mn>2</mn></msub></semantics></math></inline-formula> layers. In addition, the used preparation methods require only a limited amount of photocatalyst, little equipment, and allow easy upscaling.Ewoud CosaertCédric WolfsStéphanie D. LambertGeraldine J. HeynderickxDirk PoelmanMDPI AGarticlephotocatalysisTiO<sub>2</sub>sol–gelPEGPMMAPVPOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6584, p 6584 (2021)
institution DOAJ
collection DOAJ
language EN
topic photocatalysis
TiO<sub>2</sub>
sol–gel
PEG
PMMA
PVP
Organic chemistry
QD241-441
spellingShingle photocatalysis
TiO<sub>2</sub>
sol–gel
PEG
PMMA
PVP
Organic chemistry
QD241-441
Ewoud Cosaert
Cédric Wolfs
Stéphanie D. Lambert
Geraldine J. Heynderickx
Dirk Poelman
Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders
description Photocatalytic nanomaterials, using only light as the source of excitation, have been developed for the breakdown of volatile organic compounds (VOCs) in air for a long time. It is a tough challenge to immobilize these powder photocatalysts and prevent their entrainment with the gas stream. Conventional methods for making stable films typically require expensive deposition equipment and only allow the deposition of very thin layers with limited photocatalytic performance. The present work presents an alternative approach, using the combination of commercially available photocatalytic nanopowders and a polymer or inorganic sol–gel-based matrix. Analysis of the photocatalytic degradation of ethanol was studied for these layers on metallic substrates, proving a difference in photocatalytic activity for different types of stable layers. The sol–gel-based <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mi>TiO</mi><mn>2</mn></msub></semantics></math></inline-formula> layers showed an improved photocatalytic activity of the nanomaterials compared with the polymer <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mi>TiO</mi><mn>2</mn></msub></semantics></math></inline-formula> layers. In addition, the used preparation methods require only a limited amount of photocatalyst, little equipment, and allow easy upscaling.
format article
author Ewoud Cosaert
Cédric Wolfs
Stéphanie D. Lambert
Geraldine J. Heynderickx
Dirk Poelman
author_facet Ewoud Cosaert
Cédric Wolfs
Stéphanie D. Lambert
Geraldine J. Heynderickx
Dirk Poelman
author_sort Ewoud Cosaert
title Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders
title_short Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders
title_full Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders
title_fullStr Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders
title_full_unstemmed Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders
title_sort deposition of hybrid photocatalytic layers for air purification using commercial tio<sub>2</sub> powders
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/9d35bf0d190a43cf81aa105f4e7e1cf9
work_keys_str_mv AT ewoudcosaert depositionofhybridphotocatalyticlayersforairpurificationusingcommercialtiosub2subpowders
AT cedricwolfs depositionofhybridphotocatalyticlayersforairpurificationusingcommercialtiosub2subpowders
AT stephaniedlambert depositionofhybridphotocatalyticlayersforairpurificationusingcommercialtiosub2subpowders
AT geraldinejheynderickx depositionofhybridphotocatalyticlayersforairpurificationusingcommercialtiosub2subpowders
AT dirkpoelman depositionofhybridphotocatalyticlayersforairpurificationusingcommercialtiosub2subpowders
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