Synthesis and X-ray characterization of 15- and 16-vertex closo-carboranes

The synthesis of closo-carboranes with more than 14 vertexes is challenging, and no examples have been reported to date. Herein, the authors present the long-sought 15- and 16-vertex closo-carboranes, in which the introduction of silyl groups to the two cage carbons is crucial; this finding might en...

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Autores principales: Fangrui Zheng, Tsz Hin Yui, Jiji Zhang, Zuowei Xie
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/a22c8b1be7e64300b37f29e9f89a3889
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