Synthesis and X-ray characterization of 15- and 16-vertex closo-carboranes

The synthesis of closo-carboranes with more than 14 vertexes is challenging, and no examples have been reported to date. Herein, the authors present the long-sought 15- and 16-vertex closo-carboranes, in which the introduction of silyl groups to the two cage carbons is crucial; this finding might en...

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Autores principales:	Fangrui Zheng, Tsz Hin Yui, Jiji Zhang, Zuowei Xie
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/a22c8b1be7e64300b37f29e9f89a3889
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id	oai:doaj.org-article:a22c8b1be7e64300b37f29e9f89a3889
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spelling	oai:doaj.org-article:a22c8b1be7e64300b37f29e9f89a38892021-12-02T13:57:34ZSynthesis and X-ray characterization of 15- and 16-vertex closo-carboranes10.1038/s41467-020-19661-52041-1723https://doaj.org/article/a22c8b1be7e64300b37f29e9f89a38892020-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-19661-5https://doaj.org/toc/2041-1723The synthesis of closo-carboranes with more than 14 vertexes is challenging, and no examples have been reported to date. Herein, the authors present the long-sought 15- and 16-vertex closo-carboranes, in which the introduction of silyl groups to the two cage carbons is crucial; this finding might enable the synthesis of even larger carborane analogs in the future.Fangrui ZhengTsz Hin YuiJiji ZhangZuowei XieNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-5 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Fangrui Zheng Tsz Hin Yui Jiji Zhang Zuowei Xie Synthesis and X-ray characterization of 15- and 16-vertex closo-carboranes
description	The synthesis of closo-carboranes with more than 14 vertexes is challenging, and no examples have been reported to date. Herein, the authors present the long-sought 15- and 16-vertex closo-carboranes, in which the introduction of silyl groups to the two cage carbons is crucial; this finding might enable the synthesis of even larger carborane analogs in the future.
format	article
author	Fangrui Zheng Tsz Hin Yui Jiji Zhang Zuowei Xie
author_facet	Fangrui Zheng Tsz Hin Yui Jiji Zhang Zuowei Xie
author_sort	Fangrui Zheng
title	Synthesis and X-ray characterization of 15- and 16-vertex closo-carboranes
title_short	Synthesis and X-ray characterization of 15- and 16-vertex closo-carboranes
title_full	Synthesis and X-ray characterization of 15- and 16-vertex closo-carboranes
title_fullStr	Synthesis and X-ray characterization of 15- and 16-vertex closo-carboranes
title_full_unstemmed	Synthesis and X-ray characterization of 15- and 16-vertex closo-carboranes
title_sort	synthesis and x-ray characterization of 15- and 16-vertex closo-carboranes
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/a22c8b1be7e64300b37f29e9f89a3889
work_keys_str_mv	AT fangruizheng synthesisandxraycharacterizationof15and16vertexclosocarboranes AT tszhinyui synthesisandxraycharacterizationof15and16vertexclosocarboranes AT jijizhang synthesisandxraycharacterizationof15and16vertexclosocarboranes AT zuoweixie synthesisandxraycharacterizationof15and16vertexclosocarboranes
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Synthesis and X-ray characterization of 15- and 16-vertex closo-carboranes

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